旋流阻塞与旋流扩散复合内消能泄洪洞的壁面压强特性

结合雅砻江两河口水电站3#导流洞改建的水工模型试验,研究了新型旋流阻塞和旋流扩散复合内消能泄洪洞的壁面压强特性。研究结果表明:在淹没堰流流态时,壁面压强在进口的堰面、竖井段和旋流洞段因阻塞的顶托作用整体增大;在起旋器出口下游侧的旋流洞的顶部仍然存在局部范围的低压区或负压区;在旋流阻塞段,流速增大,壁面压强减小,水流空化数降低;在旋流扩散段,壁面压强略大于或小于大气压。     

Construction and cosmic-ray test of the new inner drift chamber for BESIII

A new inner drift chamber has been built which can replace the aged part of the BESIII drift chamber when needed. The design of the new inner drift chamber can minimize the ineffective area in the very forward and backward region and hence reduce the background event rate. With this design, the new inner drift chamber is expected to have a longer lifetime and improved performance due to the lower occupancy. The endplates and the cylinder were machined with high precision. Wire stringing was performed after the mechanical structure was assembled, and good quality of wire stringing was ensured by measurement of the tension and leakage current of the wires. After completion of the physical construction of the new chamber, a cosmic-ray test was carried out to test its performance. The results of the cosmic-ray test show that the new inner chamber achieves a spatial resolution of127 μm and a d E/dx resolution of 6.4%, which satisfies the design specifications.     

1.0 MeV电子碰撞引起Ta 和Au 内壳电离截面的测量

无论对深入理解电子-原子的作用机制,还是在材料等领域的实际应用,电子轰击原子的内壳电离截面都具有重要意义。当前电子碰撞引起原子内壳电离的实验数据多集中在几十keV 入射能量和中小Z 靶原子,其它数据相对比较缺乏。本工作以能量为1.0 MeV电子轰击Ta 和Au 靶,通过测量靶原子特征X射线的产额,获得其K壳电离截面分别为13.3 和10.1 b,L 壳电离截面分别为554 和338 b。并将实验结果和相应的理论进行了对比,结果显示,本实验测得的K壳电离截面与Casnati、Hombourger 理论值、L 壳电离截面与Scoeld和Born-Bethe 的理论值相符。Accurate experimental data for atomic inner-shell ionization cross-sections by electrons are of basic importance both in understanding inelastic electron-atom interaction and its application. Up to now, most of available data on this process were mainly concentrated on the low and medium Z atoms by the bombardment of low energy electrons. In present experiments K-shell and L-shell ionization cross-sections of Ta and Au in collisions with 1.0 MeV eleltron were determined by measuring the characteristic X-rays emitted from the target atoms. For the present collision systems the K-shell ionization cross-sections were found to be 13.3 and 10.1 b,and the L-shell ionization cross sections were 554 and 338 b, respectively. The measured K-shell ionization cross sections are in reasonable agreement with the theoretic predictions of Casnati and Hombourger, while L-shell ionization cross sections are consistent with the theoretical results of Soc eld and Born-Bethey.     

Aqueous Phase Sensing of Fe3+ and Ascorbic Acid by a Metal–Organic Framework and Its Implication in the Construction of Multiple Logic Gates

A new Hf^IV‐based metal‐organic framework with UiO‐66 topology was synthesized via a one‐step solvothermal method by using 3‐methyl‐4‐phenylthieno[2,3‐b]thiophene‐2,5‐dicarboxylic acid (H₂MPTDC) as a ligand. The MOF material showed a high stability in a broad pH range (from pH 2 to pH 12) in an aqueous medium. The presence of hydrophobic methyl and phenyl substituents in the carboxylic acid ligand and strong Hf?O bond play crucial roles in its stability. The new MOF material was systematically characterized by various techniques such as XRPD, N₂ sorption, thermogravimetric analyses and FT‐IR spectroscopy. The photophysical properties of the MOF material were also examined by steady‐state and time‐resolved fluorescence studies. It was observed that the blue fluorescence of the MOF material was selectively quenched in the presence of Fe³⁺ ion in pure aqueous medium. A mechanistic study disclosed that quenching occurs via a strong inner filter effect (IFE) arising from Fe³⁺ ion in aqueous medium. Interestingly, the fluorescence of the MOF material can be recovered by elimination of the IFE of Fe³⁺ ion via reduction of Fe³⁺ ion by ascorbic acid (AA). Based on the fluorescence recovery by AA, a MOF based on‐off‐on probe was developed for the sensing of Fe³⁺ ion and AA in aqueous medium. Inspired by this reversible sensing event, we demonstrate basic (NOT, OR, YES, INHIBIT and IMP) and higher integrated logic operations utilizing this fluorescent MOF. This MOF‐based logic systems could be potentially used for next‐generation logic‐gate based analytical applications as well as for the detection and discrimination of targeted molecules in various complex domains.     

AN IDEA OF IMPROVING INNER WHEEL DIFFERENCE PROBLEM OF SEMI-TRAILER TRUCK

基于降低货车内轮差安全隐患的考虑,根据已有的研究成果对半挂车内轮差问题改善方向提出设想,基于刚体运动学原理提出具体改进方案,导出转弯时半挂车运动轨迹方程,运用Matlab软件从理论上进行了验证。     

Cocycle Perturbation on Banach Algebras

Let $α$ be a flow on a Banach algebra$\mathcal{B}$, and $t → u_t$ a continuous function from$\boldsymbol{R}$into the group of invertible elements of$\mathcal{B}$such that $u_sα_s(u_t) = u_{s+t}, s, t ∈ \boldsymbol{R}$. Then $β_t$ = Ad$u_t ◦ α_t$, $t ∈ \boldsymbol{R}$ is also a flow on $\mathcal{B}$, where Ad$u_t(B) \triangleq u_tBu^{−1}_t$ for any $B ∈ \mathcal{B}$. $β$ is said to be a cocycle perturbation of $α$. We show that if $α$, $β$ are two flows on a nest algebra (or quasi-triangular algebra), then $β$ is a cocycle perturbation of $α$. And the flows on a nest algebra (or quasi-triangular algebra) are all uniformly continuous.     

一种复杂多边形最大内圆的快速查找算法

任意多边形的最大内圆的快速查找在多个领域有着重要的应用。首先给出了任意多边形的Voronoi图的生成方法,以及基于Voronoi图实现该多边形的最大内圆的寻找算法,在此基础上分别采用中线简化及并行化处理对算法进行了效率方面的改进,并重点研究了矢量数据并行化过程中的数据分配策略,给出了其最优数据划分策略——算法复杂度均衡法。最后对北美阿拉斯加地区的多个湖泊进行了最大内圆的查找实验,相应的实验结果表明,改进的方法能够很大程度地提高最大内圆的查找效率。     

黏弹性准饱和土中球空腔动力特性

在频率域内研究了内水压力作用下分数导数型黏弹性准饱和土中球空腔的稳态动力响应. 通 过引入与孔隙率有关的应力系数合理地确定了介质和孔隙水共同承担的内水压力值. 将土骨 架和衬砌分别视为具有分数导数本构模型的黏弹性体和多孔柔性材料, 基于Biot两相介质模 型, 通过引入位移势函数解耦得到了内水压力作用下分数导数型黏弹性准饱和土中半封闭球 形空腔的位移、应力和孔隙水压力解析表达式. 考察了物性和几何各参数对球形空腔动力响 应的影响, 结果表明: 分数导数本构模型更合理地描述了土体的动力学行为; 饱和度对应力 和孔隙水压力影响较大, 而对位移影响较小.     

液粒凝固过程的动力学理论

在平均场的概念下对液态粒子的凝固过程提出了一个简化的液-固-气-雾(LSGF)数学模型,并在小过冷度的条件下,求出了有关初值问题的一致有效渐近解. 结果表明:整个动力学过程可以分为两个相互联结的时间阶段. (1) 液粒初始温度分布的瞬态过渡阶段. 在这个阶段,凝固尚未正式启动,只是系统内的温度从任意给定的初始分布迅速调整到某一特定空间分布. (2)液粒向固粒转变阶段. 在这一阶段,液-固两相开始分离,相界面逐渐向液粒中心传播,直至液相完全消失. 进而以铜为例,讨论了液态粒子在不同生长条件与物理参数下的凝固时间与凝固过程中的温度分布的演化规律.      

质子化双氧/硫杂卟啉内氢原子迁移反应的理论研究

在确定各反应体系反应物、产物稳定构象的基础上, 采用B3LYP/6-31G**方法在Gaussian 03程序下, 对质子化的双氧/硫杂卟啉的内氢迁移(IHAT)反应进行研究, 寻找并优化相应的过渡态, 比较其迁移反应速率的差异. 计算结果表明, 质子化双氧/硫杂卟啉的构象稳定性仍然是由芳香性、空间位阻、静电作用共同决定的. 质子化后的双取代体系的内氢迁移反应速率大小差异显著, 内环取代对IHAT反应速率的影响主要来源于电子效应, 而非构象变化; 且双取代对体系IHAT反应速率的影响要远大于单取代.